Yes. When you import your recipient directly from a CSV, you can automatically verify them as they are being added to the campaign.
If you add your recipients from a list of leads you already have, you need to make sure that list has already been verified, either when it was imported or from the list's Actions menu (more information can be found in the Leads help article).
You can then filter the list on the verification status.
Email verified as invalid will not be added to a campaign or sent, no matter then verification method you choose.